Alin George Moldoveanu was a surprise winner in the men's 10m air rifle final at the Royal Artillery Barracks.
India's Gagan Narang won the Olympic bronze medal with a total of 701.1
Italian Campriani and Moldoveanu, who is
ranked outside the world's top 25, had both set Olympic record-equalling
scores of 599 in qualification.
On the third day of shooting competition at the Woolwich venue, Peter Hellenbrand of the Netherlands shot the first maximum 10.9 but was forced to settle for fifth.
British marksman James Huckle had earlier missed out on a place in the final, his total of 593 out of 600 not enough to secure a top-eight finish.
Narang's bronze provided some consolation for the hundreds of Indian supporters in the rifle range following defending Olympic champion Abhinav Bindra's failure to progress.
Bindra, who became India's first individual Olympic gold medallist in Beijing in 2008, finished 16th in qualification.
BBC
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